Citation: DING Ai-Xiang, JIA Wen-Bin, ZHANG Gao-Bin, PAN Jian-Ting, ZHANG Yu-Yang, YANG Jia-Xiang. Synthesis, Crystal Structure, and Photoluminescence Properties of One Novel D-π-D Type α-Cyanostilbene Derivative[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1239-1244. shu

Synthesis, Crystal Structure, and Photoluminescence Properties of One Novel D-π-D Type α-Cyanostilbene Derivative

1.
Department of Chemistry, Anhui University, Hefei 230601, China

Received Date: 18 February 2014
Available Online: 22 May 2014
Fund Project: Supported by the Natural Science Foundation of Anhui Province (1208085MB21) (1208085MB21)

Researches on α-cyanostilbene derivatives demonstrated them to be promising AIE or AIEE structural molecules and potential photoelectric materials. One novel α-cyanostilbene derivative, namely (E)-2-(4-butoxyphenyl)-3-(4-(diethylamino)phenyl)acrylonitrile (BPDPA), has been designed, synthesized and characterized. The crystalline structure of BPDPA has been studied in detail. The single-crystal X-ray diffraction revealed BPDPA crystallizes in triclinic space group P1, with a=12.860(5), b=13.327(5), c=15.016(5) Å, α=72.650(5), β=66.969(5), γ=62.897(5)°, M_r=696.95, V=2085.6(13) Å³, Z=2, D_c=1.110 g/cm^-3, μ=0.068 mm^-1, F(000)=752, R_int=0.0264, R(I>2σ(I))=0.0649, wR (I>2σ(I)=0.1724, R(all data)=0.1321, wR(all data)=0.2158, completeness to theta=25.00 is 99.4% and GOF=1.067. Like most reported α-cyanostilbene derivatives, BPDPA possesses a somewhat twisted molecular structure. UV-Vis and FL measurements showed an obviously bathochromic effect of BPDPA with increasing the polarity of the solvents.
- α-cyanostilbene,
- synthesis,
- crystal structure,
- UV-Vis and FL
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