Citation: MEI Chong-Zhen, LI Hai-Hua, MENG Rui-Jing, MEI Shi-Le, XIONG Han-Lin. A Novel 3D Supramolecular Framework of Poly[(5-(oxidediphenylphosphino)isophthalate)zinc(Ⅱ)]: Syntheses and Structure[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1199-1206. shu

A Novel 3D Supramolecular Framework of Poly[(5-(oxidediphenylphosphino)isophthalate)zinc(Ⅱ)]: Syntheses and Structure

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a. Institute of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, China;
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b. Key Lab. of Northwest Water Resources and Environment Ecology of MOE at Xi'an University of Technology, Xi'an 710048, China

Corresponding author: MEI Chong-Zhen,
Received Date: 11 February 2014
Available Online: 28 May 2014
Fund Project: the National Natural Science Foundation of China (No. 5119003) (No. 124300510050)

A novel metal-organic framework, namely [Zn(C₂₀H₁₃O₅P)]_n (1), has been hydrothermally synthesized through the reaction of 5-(oxidediphenylphosphino)isophthalic acid (H₂L) with Zn(Ⅱ) salt. The title compound crystallizes in monoclinic, space group P2₁/c with a=11.0966(10), b=14.5651(14), c=14.7311(15) Å, β=130.022(6)°, C₂₀H₁₃O₅PZn, M_r=429.64, V=1823.3(3) Å³, D_c=1.565 g/cm³, F(000)=872, μ=1.463 mm^-1, S=1.054 and Z=4. The final R=0.0270 and wR=0.0739 for 2769 observed reflections with I>2σ(I). In the title complex, the Zn₂(CO₂)₂ binuclear clusters are linked by L^2- ligands to result in a pillared layer structure in the bc plane, which is a (4,4)-net composed of helical chains with opposite chirality by sharing Zn₂(CO₂)₂ units. Adjacent layers are further associated together through Zn-O bonds involving the metal center and the oxygen atom of P=O group to achieve a 3D architecture, in which one-dimensional quadrangled channel displays the interweaving of two pairs of coaxial double-helical chains with opposite chirality. The luminescence property and thermogravimetric analysis of the title complex were investigated.
- 5-(oxidediphenylphosphino)isophthalic acid,
- coaxial double-helical chains,
- opposite chirality
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