Citation: SANG Rui-Li, XU Li. Syntheses and Crystal Structures of a Cadmium(Ⅱ) and a Zinc(Ⅱ) Complexes with the Flexible Ligand 1-Acetic Acid-2, 2'-biimidazole[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1147-1153. shu

Syntheses and Crystal Structures of a Cadmium(Ⅱ) and a Zinc(Ⅱ) Complexes with the Flexible Ligand 1-Acetic Acid-2, 2'-biimidazole

SANG Rui-Li ,
XU Li ^,

1.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: XU Li,
Received Date: 29 November 2013
Available Online: 19 June 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (No. #21003125, 21073190) (No. #21003125, 21073190)the Natural Science Foundation of Fujian Province (2010 J01057) (2010 J01057)

Reactions of NaAcebiim (NaAcebiim=1-acetic acid-2, 2'-biimidazole monosodium salt) and cadmium or zinc nitrate produce two supramolecular architectures, namely, 1D [Cd(Acebiim)(NO₃)(H₂O)]n (1) and 0D [Zn(Acebiim)₂(H₂O)₂]·2H₂O (2) in acidic aqueous solutions. Single-crystal X-ray diffraction analysis reveals that complex 1 crystallizes in the triclinic system, space group P1, and 2 is of monoclinic system, space group P2₁/n. In 1, two nitrate groups link two Cd(Ⅱ) ions forming [Cd₂(NO₃)₂(H₂O)₂] as secondary building units that are interconnected by the Acebiim-ligand into an infinite ladder. In 2, the hydrogen-bonded synthon R₂²(16) between the N-H moieties and carboxylic acid link [Zn(Acebiim)₂(H₂O)₂], generating a 1D-extended ribbon. Moreover, hydrogen bonds and π-π interactions further stabilize the 3D supramolecular architecture.
- crystal structure,
- supramolecular architecture,
- hydrogen bond,
- biimidazole,
- organic-inorganic hybrid composite
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