Citation: HUANG Qiu-Ping, LI Gui, ZHANG Shu-Hua, ZHANG Hai-Yang. A New Tetranuclear Cobalt Cluster with (1H-Benzimidazol-2-yl)-methanol Synthesis and Crystal Structure[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1135-1140. shu

A New Tetranuclear Cobalt Cluster with (1H-Benzimidazol-2-yl)-methanol Synthesis and Crystal Structure

1.
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China

Corresponding author: ZHANG Shu-Hua,
Received Date: 10 December 2013
Available Online: 24 January 2014
Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21161006) (No. 21161006) Program for Excellent Talents in Guangxi Higher Education Institutions (Gui Jiao Ren [2012]41) (Gui Jiao Ren [2012]41)

A new tetranuclear cluster [Co₄(bm)₆Cl₂]·(H₂O)₂·(CH₃OH) (1, Hbm is (1H-benzimidazol-2-yl)-methanol) has been synthesized by solvothermal method and structurally determined by IR, elemental analysis, and single-crystal X-ray diffraction. Complex 1 belongs to monoclinic space group P2₁/n with a=21.1713(5), b=12.7948(3), c=24.0195(9) Å, β=95.309(3)°, V=6478.6(3) Å³, Z=4, F(000)=2568, D_c=1.289 g·cm^-3, M_r=1257.63, μ=9.096 mm^-1, S=1.000, the final R=0.0861 and wR=0.2552 for 4956 observed reflections with I>2σ(I). Two connected face-sharing cubes are observed in the framework of 1, each with one vertex missing. Complex 1 forms a 2-D network through N-H…O hydrogen bonds. The apparent holes can be observed.
- (1H-Benzimidazol-2-yl)-methanol,
- tetranuclear cluster,
- crystal structure
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