Citation: LI Huan-Huan, LIU Li, MING Chun-Lun, CUI Guang-Hua. Synthesis and Characterization of a Two-dimensional Cadmium(Ⅱ) Metal Organic Framework with Fes Topology[J]. Chinese Journal of Structural Chemistry, ;2014, 33(7): 1050-1056. shu

Synthesis and Characterization of a Two-dimensional Cadmium(Ⅱ) Metal Organic Framework with Fes Topology

1.
College of Chemical Engineering, Hebei United University, Tangshan, Hebei 063009, China

Corresponding author: CUI Guang-Hua,
Received Date: 19 December 2013
Available Online: 26 January 2014
Fund Project: This project was supported by the Youth Foundation of Hebei Province (E2012401070) (E2012401070)

A new Cd(Ⅱ) coordination polymer, {[Cd(Hnbta)(L)]·H₂O}_n (L=1,4-bis(5,6-dimethylbenzimidazol-1-yl)butane), H₃nbta=5-nitrobenzene-1,2,3-tricarboxylic acid), has been hydro-thermally synthesized and characterized by elemental analyses, IR, XRPD, and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P2₁/n with a=17.3056(13), b=11.0114(9), c=17.7484(14) Å, β=117.3640(10)°, V=3003.7(4) Å³, Z=4, C₃₁H₃₁CdN₅O₉, M_r=730.01, D_c=1.614 g/cm³, μ=0.792 mm^-1 and F(000)=1488. The cadmium(Ⅱ) ions are bridged by Hnbta^2- to generate a two-dimensional metal organic framework with fes topology. In addition, the thermal stability and fluorescence properties of the complex were also studied.
- Cd(Ⅱ) complex,
- crystal structure,
- fluorescence property,
- 5-nitrobenzene-1,2,3-tricarboxylic acid
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