Citation: YANG Hua, HU Dao-Dao. Synthesis, Structure, and Luminescent Property of a 3-D Zinc Complex {[Zn₈^Ⅱ(4-APha)₈(CH₃COO)₈](CH₃CH₂OH)₂}_n[J]. Chinese Journal of Structural Chemistry, ;2014, 33(7): 1019-1024. shu

Synthesis, Structure, and Luminescent Property of a 3-D Zinc Complex {[Zn₈^Ⅱ(4-APha)₈(CH₃COO)₈](CH₃CH₂OH)₂}_n

YANG Hua ^a,b ,
HU Dao-Dao ^b,,

a.
a. College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China;
b.
b. School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, Shaanxi 710062, China

Corresponding author: HU Dao-Dao,
Received Date: 9 December 2013
Available Online: 14 February 2014
Fund Project: Supported by Department of Education of Shaanxi Province (2013JK0664) (2013JK0664)

The title complex [Zn₈^Ⅱ(4-APha)₈(CH₃COO)₈(CH₃CH₂OH)₂]_n (1, 4-APha=4-aminophenylhydroxamic acid) has been prepared under solvothermal conditions. It has been characterized by X-ray single-crystal diffraction, IR and elemental analysis. The crystal belongs to the monoclinic system, space group C2/c with a=39.074(4), b=9.9645(8), c=38.846(3) Å, β=136.438°, V=10423.1(14) Å³, C₈₄H₁₁₈N₁₆O₃₉Zn₈, M_r=2498.90, Z=4, D_c=1.592 g/cm³, μ=1.900 mm^-1, F(000)=5144, the final R=0.1036 and wR=0.2953. This complex possesses a 3-D structure which is constructed from 1-D chain motifs linked by the 4-APha^- ligands. The luminescent property of the title complex has been investigated.
- zinc complex,
- hydroxamic acids,
- 3-D framework,
- luminescent property
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