Citation: Xiang Ping HU, Hui Lin CHEN, Hui Cong DAI, Xin Quan HU, Zhuo ZHENG. Synthesis and Potential Application of Novel C₂-Symmetrical Bis(ferrocenyl) P₂N Ligand[J]. Chinese Chemical Letters, ;2003, 14(11): 1113-1115. shu

Synthesis and Potential Application of Novel C₂-Symmetrical Bis(ferrocenyl) P₂N Ligand

Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023

Received Date: 1 November 2002

Fund Project: This work was supported by the National Natural Science Foundation of China (29933050).

A novel chiral bis(ferrocenyl) P₂N ligand 1 with C₂-symmetry was synthesized through a four-step procedure from (R)-N,N-dimethyl-1-ferrocenylethylamine. In a model reaction of Pd-catalyzed allylic alkylation of 1,3-diphenylprop-2-enyl acetate 6 with dimethyl malonate, good enantioselectivity (86% e.e.) was obtained.
- Synthesis,
- C₂-symmetry,
- bis(ferrocenyl) P₂N ligand,
- Pd-catalyzed allylic alkylation
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