Citation: XING Yuan-Yuan, CHEN Cong, SI Zhen-Jun, SHI Tao, DUAN Qian. Application of 4,4'-(2-Carboxypropane-1,3-diyl)dibenzoic Acid in Coordination Metal Complexes: Synthesis, Characterization, and Theoretical Studies[J]. Chinese Journal of Structural Chemistry, ;2014, 33(7): 971-977. shu

Application of 4,4'-(2-Carboxypropane-1,3-diyl)dibenzoic Acid in Coordination Metal Complexes: Synthesis, Characterization, and Theoretical Studies

1.
School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China

Corresponding author: SI Zhen-Jun, DUAN Qian,
Received Date: 3 January 2014
Available Online: 14 April 2014
Fund Project: This project was supported by the National Natural Science Foundation of China (No. 21271033) (No. 21271033)

[Pb(HL)(phen)]_n (1) and [Cd₃L₂(phen)]_n (2), where phen=1,10-phenanthroline and L=4,4'-(2-carboxylatopropane-1,3-diyl)dibenzoate, were hydrothermally prepared and fully characterized by X-ray single-crystal diffraction, infrared spectroscopy and thermogravimetric analyses. The decomposition temperature of 1 and 2 was measured to be ca. 304 and 416℃, respectively. The charge transfer transition based absorption of 1 and 2 was also verified by the powder scattering spectra and theoretical analyses.
- metal organic complexes,
- synthesis,
- theoretical analyses
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