Citation: WANG Qing-Wei, CHEN Lin, QI Xiao-Fei, WANG Ya-Nan, LIU Bo. A 3-fold Interpenetrated lvt Cd(Ⅱ) Network Constructed from 4-[(3-pyridyl)methylamino]benzoate Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(5): 757-763. shu

A 3-fold Interpenetrated lvt Cd(Ⅱ) Network Constructed from 4-[(3-pyridyl)methylamino]benzoate Acid

1.
Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Department of Chemistry, Jilin Normal University, Siping, Jilin 136000, China

Received Date: 7 November 2013
Available Online: 3 May 2014
Fund Project: the Science and Technology Research Projects of the Education Office of Jilin Province (No. 2013. 384) (201205080)

A new three-dimensional (3D) coordination polymer, [Cd(L)2H₂O]_n·5nH₂O 1 with 4-[(3-pyridyl)methylamino]benzoate acid (HL), has been synthesized by slow evaporation solvent at room temperature, and structurally characterized by elemental analysis, IR spectrum, thermal analysis, fluorescence spectrum and single-crystal X-ray diffraction. Compound 1 crystallizes in the tetragonal system, space group I-4, with a=20.7937(16), c=13.515(2), V=5843.5(11)Å³, C₂₆H₃₄CdN₄O₁₀, M_r=674.97, D_c=1.534 g/cm³, μ(MoKα)=0.808 mm^-1, F(000)=2768, Z=8, the final R=0.0276 and wR=0.0691 for 5323 observed reflections (I>2σ(I)). The result of thermal analysis shows that 1 is stable under 290℃ . Moreover, it exhibits blue photoluminescence at room temperature.
- 4-[(3-pyridyl)methylamino]benzoate acid,
- lvt topology,
- 3-fold interpenetrated,
- luminescent property
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