Citation: ZHANG Fu-Qing, ZHOU Jing-Jing, HUANG Qi-Mao, ZHOU Hong, PAN Zhi-Quan. Structure and Magnetic Properties of a Bipyridine-bridged One-dimensional Ni(Ⅱ) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2014, 33(5): 735-740. shu

Structure and Magnetic Properties of a Bipyridine-bridged One-dimensional Ni(Ⅱ) Coordination Polymer

1.
School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, China

Received Date: 13 February 2014
Available Online: 4 April 2014
Fund Project: We are thankful for the financial support from the National Natural Science Foundation of China (21171135) (21171135) Hubei Provincial Science & Technology Department (2011BFA020) (2011BFA020)Hubei Independent Innovation Base (HBIR07) (HBIR07)

A polymer, [NiL(bipy)·2H₂O]_n (1, bipy=4,4'-bipyridine), has been acquired by the reaction of Ni(OAc)₂·4H₂O with N,N'-bis(2-hydroxyl-5-fluorobenzyl)-2-hydrxylpropane diimine in the presence of 4,4'-bipyridine. X-ray crystallographic analysis shows that it is comprised of a mononuclear Ni(Ⅱ) complex [NiL] linked by 4,4'-bipyridine. Its crystal crystallizes in the orthorhombic system, space group C2/c with a=22.595(3), b=18.395(2), c=15.434(2)Å, V=6155(1)Å³, D_c=1.259 g/cm^-3, Z=8, M_r=583.23, F(000)=2416.0, μ(MoKa)=0.681 mm^-1, S=1.049, R=0.0512 and wR=0.1108 for 6032 observed reflections (I>2σ(I)). There are water hexamers in the complex. A weak overall ferromagnetic behavior has been evaluated by Curie-Weiss rule and by the formula of alternating ferro-ferromagnetic coupling in one-dimensional Ni(Ⅱ) chain, which gives g=2.005(1) and J₁=0.31(3) cm^-1.
- bipyridine-bridged coordination polymer,
- Ni(Ⅱ) complex,
- magnetic properties,
- water hexamer
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