Citation: WANG Ji-Jiang, TANG Long, HOU Xiang-Yang, GAO Lou-Jun, FU Feng, ZHANG Mei-Li. Synthesis, Structure and Electrochemical Property of a New 3D Ag(Ⅰ) Coordination Polymer Constructed by Biphenyl-2,2',4,4'-tetracarboxylate[J]. Chinese Journal of Structural Chemistry, ;2014, 33(5): 729-734. shu

Synthesis, Structure and Electrochemical Property of a New 3D Ag(Ⅰ) Coordination Polymer Constructed by Biphenyl-2,2',4,4'-tetracarboxylate

1.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an 716000, China

Corresponding author: WANG Ji-Jiang,
Received Date: 20 January 2014
Available Online: 20 March 2014
Fund Project: This project was supported by the National Natural Science Foundation of China (No. 21373178) (No. 21373178)the Natural Scientific Research Foundation of Shaanxi Provincial Education Office of China (No. 13JS124) (No. 13JS124)

A new 3D Ag(Ⅰ) coordination polymer, [Ag₈(btc)₂(bpp)₂]_n (1, H₄btc=biphenyl-2,2',4,4'-tetracarboxylic acid, bpp=1,2-bis(4-pyridyl)propane), has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, elemental analysis and IR spectroscopy. Complex 1 crystallizes in the triclinic system, space group P1 with a=13.4899(8), b=13.4928(8), c=16.4575(10)Å, α=102.7640(10), β=108.8100(10), γ=101.4940(10)°, V=2644.1(3)Å³, Z=2, D_c=2.401 Mg·m^-3, μ=2.978 mm^-1, F(000)=1840, the final R=0.0481 and wR=0.0955 for 6794 observed reflections with I>2σ(I). Complex 1 features a 3D framework formed by Ag (I)-carboxylate chains containing [Ag₁₆(COO)₁₆] secondary building block. Furthermore, thermal stability and electrochemical property of 1 are also investigated in detail.
- biphenyl-2,
- 2',4,4'-tetracarboxylic acid,
- Ag(Ⅰ),
- electrochemical property
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