Citation: LIU Cheng, LIU Qi-Hui, GE Shu-Bao, WU Gang. Synthesis, Structure and Properties of a New Lead(Ⅱ) Complex of 1,3-Benzenedicarboxylic Acid, 1,10-Phenanthroline and Its Thermal Decomposition to PbO Micro-crystal Particles[J]. Chinese Journal of Structural Chemistry, ;2014, 33(5): 713-720. shu

Synthesis, Structure and Properties of a New Lead(Ⅱ) Complex of 1,3-Benzenedicarboxylic Acid, 1,10-Phenanthroline and Its Thermal Decomposition to PbO Micro-crystal Particles

1.
College of Material and Chemical Engineering, Chuzhou University, Anhui 239012, China

Received Date: 4 November 2013
Available Online: 26 January 2014
Fund Project: The project was supported by Natural Science Foundation of Anhui Province (1208085MB31) (1208085MB31)

The self-assembly of 1,10-phenanthroline (phen) and 1,3-benzenedicarboxylic acid (H₂bdc) with Pb(NO₃)₂ under solvothermal conditions in N,N-dimethylacetamide (DMA) gives rise to a one-dimensional chain coordination polymer, [Pb(phen)(bdc)] (1), which was characterized by elemental analysis, FT-IR and single-crystal X-ray diffraction. This complex crystallizes in triclinic, space group P1 with a=7.5595(6), b=9.8199(8), c=13.1663(11)Å, α=69.7590(10), β=80.6000(10), γ=71.3180(10)°, Z=2, C₂₀H₁₂N₂O₄Pb, M_r=551.51, D_c=2.112 g/cm³, F(000)=520 and μ=9.757 mm^-1. The final R=0.0304 and wR=0.0763 for 3427 observed reflections with I>2σ(I) and R=0.0365 and wR=0.0894 for all data. The structure contains one crystallographic unique Pb(Ⅱ) atom, one phen molecule chelating with a Pb(Ⅱ) atom, and one bdc^2- anion, acting as a bidentate bridging ligand linking the Pb(Ⅱ) atoms to form a one-dimensional structure. The two-dimensional layer and three-dimensional stacking structures are formed by C-H…O hydrogen bonding interactions. The thermal stable and fluorescent properties of 1 were investigated. PbO micro-crystal particles are produced by calcination of powder sample of complex 1. The obtained PbO is characterized and observed by XRD and SEM analyses.
- lead complex,
- fluorescence,
- thermal stability,
- PbO
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