Citation: LI Fu-An, BAI Su-Zhen, LI Xing-Wu, CHEN Quan. Synthesis, Crystal Structure and Properties of a New Coordination Polymer Constructed with 3-(4-hydroxypyridinium-1-yl)phthalic Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(5): 701-706. shu

Synthesis, Crystal Structure and Properties of a New Coordination Polymer Constructed with 3-(4-hydroxypyridinium-1-yl)phthalic Acid

LI Fu-An ^a ,
BAI Su-Zhen ^a ,
LI Xing-Wu ^a ,
CHEN Quan ^b,,

a.
a. College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, China;
b.
b. Chemical Engineering and Pharmaceutics School, Henan University of Science and Technology, Luoyang 471023, China

Corresponding author: CHEN Quan,
Received Date: 18 October 2013
Available Online: 26 December 2013

A new nickel coordination polymer {[Ni(dpa)(bpe)(H₂O)]₂}_n (1) has been hydrothermally synthesized, and structurally characterized by UV spectroscopy, elemental analyses and single-crystal X-ray diffraction (H₂dpa=3-(4-hydroxypyridinium-1-yl) phthalic acid, bpe=μ-1,2-di(4-pyridyl) ethylene). It crystallizes in the triclinic system, space group P1 with a=8.779(2), b=10.909(3), c=12.739(3)Å, α=72.45(2), β=75.13(2), γ=86.47(2)°, V=1124.1(5)Å³, Z=2, M_r=516.14, D_c=1.525 g/cm³, μ=0.912 mm^-1,R_int=0.0532, F(000)=532, the final R=0.0523 and wR=0.1089 for 3949 observed reflections (I>2σ(I)). The coordination around the Ni center is a distorted octahedron coordination geometry involving two protonated H₂dpa ligands, two bpe ligands, and one coordinated H₂O molecule. The dpa^2- anion, as a bridging ligand, connects two Ni centers to form binuclear units, which are linked together by the bpe ligands to form two-dimensional layers, and the interlayer hydrogen bonding further extends the 2D sheet into a 3D supramolecular framework.
- 3-(4-hydroxypyridinium-1-yl) phthalic acid,
- polymer,
- binuclear nickel unit
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