Citation: LI Wei, LI Chang-Hong, LI Heng-Feng, TAN Xiong-Wen. Synthesis, Crystal Structure and Properties of the Cobalt(Ⅱ) Complex of Methyl-5-norbornene-2,3-dicarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 642-646. shu

Synthesis, Crystal Structure and Properties of the Cobalt(Ⅱ) Complex of Methyl-5-norbornene-2,3-dicarboxylic Acid

a.
a. School of Materials Science and Engineering, Central South University, Changsha 410083, China;
b.
b. Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China;
c.
c. Department of Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Corresponding author: LI Heng-Feng,
Received Date: 10 December 2013
Available Online: 1 March 2014
Fund Project: Supported by the Natural Science Foundation of Hunan Province (No.11JJ9006) (No.11JJ9006)the Construct Program of the Key Discipline in Hunan Province (2012FJ2002)

A new cobalt complex Co(C₁₀H₈N₂)(H₂O)₃[C₉H₁₁O₂(COO)] with methy-5-norbor-nene-2,3-dicarboxylic anhydride acid (MNA) and 2,2'-bipyridine as ligands has been synthesized in the mixed solvents of ethanol and water. It crystallizes in monoclinic, space group P2₁/c with a=13.0430(13), b=21.014(2), c=7.5151(7) Å, β=102.319(2)°, V=2012.4(3) Å³, D_c=1.529 g/cm³, Z=4, F(000)=964, GOOF=1.051, the final R=0.0457 and wR=0.0974. The crystal structure shows that the cobalt ion is coordinated with four oxygen atoms from one MNA molecule and three water molecules together with two nitrogen atoms from the 2,2'-bipyridine molecule, forming a distorted octahedral coordination geometry. The thermal stability and electrochemical properties have studied in this paper.
- cobalt(Ⅱ) complex,
- crystal structure,
- electrochemical properties
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