Citation: LEI Xiao-Wu, YUE Cheng-Yang, ZHANG Hui-Ping, ZHAI Xiu-Rong, FENG Li-Juan. Synthesis, Crystal Structure and Luminescent Properties of One New Ag(I) Complex Based on 3-Aminopyrazine-2-carboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 635-641. shu

Synthesis, Crystal Structure and Luminescent Properties of One New Ag(I) Complex Based on 3-Aminopyrazine-2-carboxylic Acid

1.
Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155, China

Received Date: 8 October 2013
Available Online: 22 November 2013
Fund Project:

One new Ag^I complex, [Ag(apca)(H₂O)]_n (Hapca=3-aminopyrazine-2-carboxylic acid), has been prepared and structurally and spectroscopically characterized. The title complex (1) crystallizes in the monoclinic system P2₁/c (No. 14) with a=14.3307(9), b=14.9296(9), c=6.5824(4) Å, β=92.7430(10)°, V=1406.70(15) Å³, Z=8. M_r=264.00, D_c=2.493 g/cm³, μ=2.831 mm^-1, F(000)=1024, the final R=0.0266 and wR=0.0788 for 3107 observed reflections with I>2σ(I). Its structure features a three-dimensional (3D) network composed of one-dimensional (1D) [Ag(apca)(H₂O)]_n ribbons interconnected via weak hydrogen bonds and π-π interactions. Emission spectra of the title complex in the solid state at room temperature give strong green luminescence.
- Hapca,
- Ag^I,
- crystal structure,
- luminescence
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