Citation: GAO Zhu-Qing, LI Hong-Jin, M. Kirillov Alexander, GU Jin-Zhong. Syntheses, Crystal Structures and Magnetic Properties Properties of Cobalt(Ⅱ) and Manganese(Ⅱ) Coordination Polymers Constructed from 5-(Pyridin-4-yl)Isophthalate isophthalate Ligands[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 626-634. shu

Syntheses, Crystal Structures and Magnetic Properties Properties of Cobalt(Ⅱ) and Manganese(Ⅱ) Coordination Polymers Constructed from 5-(Pyridin-4-yl)Isophthalate isophthalate Ligands

a.
a. School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021, China;
b.
b. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, The University of Lisbon, Av. Rovisco Pais, 1049-001, Lisbon, Portugal;
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c. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: GU Jin-Zhong,
Received Date: 8 October 2013
Available Online: 5 March 2014
Fund Project: Funded by the National Natural Science Foundation of Shanxi Province (No. 2013011011-6) (No. 2013011011-6)

Two coordination polymers, namely {[Co(L)(H₂O)]·H₂O}_n (1) and [Mn(L)(phen)]_n (2, H₂L=5-(pyridin-4-yl)isophthalic acid, phen=1,10-phenanthroline), have been hydrothermally synthesized and characterized by elemental analysis, IR, TG, magnetic properties, and single-crystal X-ray diffraction. 1 belongs to the triclinic system, space group P1 with a=7.2188(7), b=10.0835(8), c=10.2069(7) Å, α=113.713(7), β=99.490(7), γ=104.516(8)°, V=628.24(9) Å³, C₁₃H₁₁NCoO₆, M_r=336.16, Z=2, D_c=1.777 Mg/m³, μ(MoKα)=1.395 mm^-1, F(000)=342, S=1.041, the final R=0.0381 and wR=0.0819 for 3744 observed reflections (I>2σ(I)) and R=0.0448 and wR=0.0874 for all data. 2 belongs to the monoclinic system, space group P2/c with a=12.9185(3), b=10.4343(2), c=31.7650(6) Å, β=101.282(2)°, V=4199.08(13) Å³, C₅₀H₃₀N₆Mn₂O₈, M_r=952.68, Z=4, D_c=1.507 Mg/m³, μ(MoKα)=5.447 mm^-1, F(000)=1944, S=1.128, the final R=0.1003 and wR=0.1052 for 8247 observed reflections (I>2σ(I)) and R=0.2595 and wR=0.2625 for all data. Single-crystal X-ray diffraction studies show that compound 1 features a 2D sheet structure based on a dicobalt(Ⅱ) subunit, which is further extended into a 3D metal-organic supramolecular framework by O-H…O hydrogen bond. Compound 2 also possesses a 2D sheet, which is held together into a 3D supramolecular architecture via C-H…O hydrogen bond and π-π stacking interactions. Magnetic studies for compound 2 show antiferromagnetic coupling between the adjacent metal centers, with J=-11.8 cm^-1 and g=2.12 for 2.
- coordination polymer,
- crystal structrue,
- magnetic properties
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