Citation: LIU Xi-Hui, ZHUO Xin, LIU Chao, WANG Bin. Synthesis and Structure of One New Metal-organic Framework Based on Flexible Tetrapyridines and Aliphatic Polycarboxylate Acids[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 602-606. shu

Synthesis and Structure of One New Metal-organic Framework Based on Flexible Tetrapyridines and Aliphatic Polycarboxylate Acids

LIU Xi-Hui ^a,b ,
ZHUO Xin ^b ,
LIU Chao ^b ,
WANG Bin ^a,b

a.
a. School of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui 232001, China;
b.
b. Anhui Key Laboratory of Spin Electron and Nanomaterials, Suzhou University, Anhui 234000, China

Received Date: 9 September 2013
Available Online: 13 February 2014
Fund Project: Supported by the Natural Science Foundation of Anhui province Education Department (KJ2011Z369, KJ2012A268, KJ2013B292) (KJ2011Z369, KJ2012A268, KJ2013B292) Open Project of Anhui Key Laboratory of Spin Electron and Nanomaterials (2013YKF23, 2011YKF02, 2012YKF03) (2012SQRL207)

One new complex has been produced under solvothermal reactions of tetrakis(4-pyridyloxymethylene)methane (TPOM) with glutaric acid (GA) in the presence of nitrates of cuprum in DMF/H₂O (1:5, v/v), namely, {Cu₂(TPOM)·GA)₂}_n. The complex crystallizes in the monoclinic system, space group P2/c with a=11.556(4), b=8.713(3), c=23.602(9) Å, V=2376.5(15) Å³, C₃₅H₃₆Cu₂N₄O₁₂, M_r=831.76, Z=2, D_c=1.162 g·cm^-3, F(000)=856, μ=0.947mm^-1, R=0.0547 and wR=0.1718 (I>2σ(I)). This complex was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It is the first complex synthesized by coordinating with TPOM and catenulate aliphatic polycarboxylate acid ligands. The structural analyses show that the complex is a 2-fold interpenetrating 3D architecture.
- crystal structure,
- coordination complex,
- network structure
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