Citation: DING Yuan-Shuai, FAN Li-Ming, PANG Yue, ZHANG Xiu-Tang, TIAN Lai-Jin. Syntheses, Structures, and Properties of Three Coordination Polymers: [Cd₂(bpp)_1.5(Hbpp)(phen)₂]_n, [Mn₃(Htptc)₂(phen)₂(H₂O)₂]_n, and {[Cu(btc)_0.5(1,4-bib)]·2H₂O}_n[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 569-578. shu

Syntheses, Structures, and Properties of Three Coordination Polymers: [Cd₂(bpp)_1.5(Hbpp)(phen)₂]_n, [Mn₃(Htptc)₂(phen)₂(H₂O)₂]_n, and {[Cu(btc)_0.5(1,4-bib)]·2H₂O}_n

a.
a. College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China;
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b. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

Received Date: 15 September 2013
Available Online: 13 November 2013
Fund Project: This work was supported by the National Natural Science Foundation of China (20873150) (20873150)

Hydrothermal reactions of three aromatic polycarboxylic acids and the transitional metal cations in the presence of phen and 1,4-bib afford three new coordination polymers: [Cd₂(bpp)_1.5(Hbpp)(phen)₂]_n (1), [Mn₃(Htptc)₂(phen)₂(H₂O)₂]_n (2), and {[Cu(btc)_0.5(1,4-bib)]·2H₂O}_n (3) (H₂bpp=2,6-bis(4'-carboxyphenyl)-4-phenylpyridine, H₄tptc=terphenyl-2,5,2',5'-tetracar-boxylic acid, H₄btc=biphenyl-2,2',4,4'-tetracarboxylic acid, phen=1,10-phenanthroline, and 1,4-bib=1,4-bis(1H-imidazol-1-yl)benzene). Their structures have been determined by single-crystal X-ray diffraction analyses, elemental analyses, IR spectra, and powder X-ray diffraction (PXRD) analyses. In compound 1, the Cd^Ⅱ cations are linked by bpp^2- to form one ladder structure, based on which a 3D network is constructed with the help of non-covalent interactions. The topology of 2 is a 3D (3,4,5)-connected framework with the Point Schläfli symbol of (4².6)₂(4³.6².8)(4⁵.6⁴.8)₂. Compound 3 shows an unprecedented 3D (4,4)-connected framework with the Point Schläfli symbol of (6⁴.8²)₂(6⁵.8). Moreover, the luminescent property of 1 has been investigated.
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