Citation: CHEN Shui-Sheng, QIAO Rui, SHENG Liang-Quan, YANG Song. A New Three-dimensional Supramolecular Polymer Built from Non-covalent Bonding Interactions[J]. Chinese Journal of Structural Chemistry, ;2014, 33(4): 557-562. shu

A New Three-dimensional Supramolecular Polymer Built from Non-covalent Bonding Interactions

1.
College of Chemistry & Chemical Engineering, Fuyang Normal College, Fuyang 236041, China

Received Date: 22 September 2013
Available Online: 1 November 2013
Fund Project:

A new complex, [Ni₂(L)₄(H₂O)₈](1, L1=4-(1H-imidazol-4-yl)benzoic acid), has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and PXRD. Complex 1 crystallizes in monoclinic, space group P2₁/c with a=22.281(2), b=7.3959(7), c=24.978(3) Å, β=90.876(10), V=4115.6(7) Å³, Z=8, C₂₀H₂₂N₄O₈Ni, M_r=505.13, D_c=1.630 g/cm³, μ=1.001 mm^-1, S=1.080, F(000)=2096, the final R=0.452 and wR=0.1152 for 9380 observed reflections (I>2σ(I)). The result of X-ray diffraction analysis revealed three different kinds of Ni(Ⅱ) centre mononuclear molecules in the asymmetric unit. The independent mononuclear units are bridged to form a three-dimensional supramolecular polymer by extensive hydrogen bonds and C-H…π non-covalent bonding interactions.
- synthesis,
- supramolecular polymer,
- non-covalent bonding interactions
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