Citation: Gang LIU, Feng HE, Yan Ping WANG, Jun FENG, Ren Xi ZHUO. Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups[J]. Chinese Chemical Letters, ;2006, 17(1): 137-139. shu

Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups

Key Laboratory of Biomedical Polymers of Ministry of Education, Department of Chemistry, Wuhan University, Wuhan 430072

Received Date: 8 May 2005

Fund Project: The authors are grateful for the financial support of the National Natural Science Foundation of China (Grant No. 20104005).

A new six-membered cyclic carbonate monomer, 5-allyloxytrimethylene carbonate (ATMC), was synthesized starting from glycerol, and the corresponding polycarbonates, poly(5-allyloxytrimethylene carbonate)(PATMC) were further synthesized by ring-opening polymerization in bulk at 150℃ using stannous octanoate as an initiator. The structures of the monomer and the polymers were confirmed by IR, ¹H-NMR, ¹³C-NMR, and GPC analysis.
- 5-Allyloxytrimethylene carbonate,
- poly(5-allyloxytrimethylene carbonate),
- ring-opening polymerization,
- polycarbonate,
- allyl ether
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