Synthesis and Characterization of Star-branched Polyisobutylene by Combination of Anionic Polymerization and Cationic Polymerization

Hai Feng LIU Yang LI Yu Rong WANG Yan REN Zhan Xia LU Jin Bo ZHAO

引用本文: Hai Feng LIU,  Yang LI,  Yu Rong WANG,  Yan REN,  Zhan Xia LU,  Jin Bo ZHAO. Synthesis and Characterization of Star-branched Polyisobutylene by Combination of Anionic Polymerization and Cationic Polymerization[J]. Chinese Chemical Letters, 2006, 17(8): 1117-1120. shu
Citation:  Hai Feng LIU,  Yang LI,  Yu Rong WANG,  Yan REN,  Zhan Xia LU,  Jin Bo ZHAO. Synthesis and Characterization of Star-branched Polyisobutylene by Combination of Anionic Polymerization and Cationic Polymerization[J]. Chinese Chemical Letters, 2006, 17(8): 1117-1120. shu

Synthesis and Characterization of Star-branched Polyisobutylene by Combination of Anionic Polymerization and Cationic Polymerization

  • 基金项目:

    This work was sponsored by the China Petrochemical Corporation (No. 404038).

摘要: A star-shaped multifunctional styrene-isoprene copolymer was synthesized with n-BuLi as initiator, divinyl benzene as coupling agent, cyclohexane as solvent by living anionic polymerization.Using this polymer as grafting agent, a novel star-shaped branched polymer, containing several polyisobutylene, was prepared via cationic polymerization.The star PS-b-PI and star-branched polyisobutylene were characterized by GPC, 1HNMR and FT-IR, and the effects of different adding order and the amount of grafting agent were investigated.

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  • 收稿日期:  2006-01-23
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