Citation: Bing YAN, Hong Jie ZHANG, Jia Zuan NI. The Synthesis,Luminescence and Energy Transfer of the Binary and Ternary Complexes of Rare Earth with Aminobenzoic Acids and 1,10-Phenanthroline[J]. Chinese Chemical Letters, ;1997, 8(4): 353-356. shu

The Synthesis,Luminescence and Energy Transfer of the Binary and Ternary Complexes of Rare Earth with Aminobenzoic Acids and 1,10-Phenanthroline

Labortory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 17 December 1996

Fund Project: The authors are grateful to the National Nature Science Foundation of China and the President Foundation of Chinese Academy of Science for financial support.

Thirteen kinds of binary and ternary complexes of rare earth (Gd,Eu,Tb) with ortho (para) aminobenzoic acid and 1,10——phenanthroline were synthesized and characterized.The phosphorescence spectra and lifetimes of gadolinium complexes were measured and the lowest triplet state energies of ligands and the energy transfer efficiencies between ligands were determined.The luminescence properties and intramolecular energy transfer of these complexes were studied in details.
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