Citation: Zhi Huan WENG, Jin Yan WANG, Xi Gao JIAN. Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide[J]. Chinese Chemical Letters, ;2006, 17(6): 848-850. shu

Heteropolymolybdate as a New Reaction-controlled Phase-transfer Catalyst for Efficient Alcohol Oxidation with Hydrogen Peroxide

Department of Polymer Science and Materials, Dalian University of Technology, Liaoning High Performance Polymer Engineering Research Center, Dalian 116012

Received Date: 7 December 2005

Fund Project: This work was financially supported by the National High Technology Research and Development Program of China (863 Program) (No. 2003AA33G030).

A new catalytic process for the synthesis of aldehyde from alcohol by oxidation with H₂O₂ with high selectivity was studied. In this system, heteropolymolybdate [C₇H₇N(CH₃)₃]₃{PO₄[MoO(O₂)₂]₄} was utilized as the reaction-controlled phase-transfer catalyst to catalyze oxidation of benzyl and aliphatic alcohols. The molar ratio of H₂O₂ and alcohol was 0.75, no other by-products were detected by gas chromatography, the results of oxidation reaction indicated that the catalyst has high activity and stability.
- Heteropolymolybdate,
- reaction-controlled phase-transfer,
- alcohol,
- oxidation
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