Synthesis of a water-soluble macromolecular light stabilizer containing hindered amine structures

Wei Ma Mei Meng Xue Jiang Bing-Tao Tang Shu-Fen Zhang

Citation:  Wei Ma, Mei Meng, Xue Jiang, Bing-Tao Tang, Shu-Fen Zhang. Synthesis of a water-soluble macromolecular light stabilizer containing hindered amine structures[J]. Chinese Chemical Letters, 2013, 24(2): 153-155. shu

Synthesis of a water-soluble macromolecular light stabilizer containing hindered amine structures

    通讯作者: Wei Ma,
    Shu-Fen Zhang,
  • 基金项目:

    The authors gratefully thank the financial support of the National Natural Science Foundation of China (Nos. 20806013, 20923006)  (Nos. 20806013, 20923006)

    the National Key Technology R&D Program (No. 2011BAE07B08). (No. 2011BAE07B08)

摘要: A novel water-soluble macromolecular light stabilizer was synthesized by grafting 2-chloro-4,6-bis-[(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazine onto polyvinylamine. The intermediate 2-chloro-4,6-bis-[(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazine and the obtained macromolecular light stabilizer were characterized by 1H NMR, HRMS, IR and UV spectroscopy. Cotton fabrics dyed with C.I. Reactive Yellow 145, C.I. Reactive Red 195 and C.I. Reactive Blue 19 were finished with the macromolecular light stabilizer, and the lightfastness of the dyes was tested. The results showed that the lightfastness of the reactive dyes was improved by 0.5-1.0 grade after being finished and the macromolecular light stabilizer exhibited good wash fastness and thermal stability.

English

  • 
    1. [1] S.N. Batchelor, D. Carr, C.E. Coleman, et al., The photofading mechanism of commercial reactive dyes on cotton, Dyes Pigm. 59 (2003) 269-275.[1] S.N. Batchelor, D. Carr, C.E. Coleman, et al., The photofading mechanism of commercial reactive dyes on cotton, Dyes Pigm. 59 (2003) 269-275.

    2. [2] N.S.E. Ahmed, The use of sodium edate in the dyeing of cotton with reactive dyes, Dyes Pigm. 65 (2005) 221-225.[2] N.S.E. Ahmed, The use of sodium edate in the dyeing of cotton with reactive dyes, Dyes Pigm. 65 (2005) 221-225.

    3. [3] J.A. Taylor, Recent developments in reactive dyes, Rev. Prog. Color. 30 (2000) 93-108.[3] J.A. Taylor, Recent developments in reactive dyes, Rev. Prog. Color. 30 (2000) 93-108.

    4. [4] T. Hihara, Y. Okada, Z. Morita, Relationship between photochemical properties and colourfastness due to light-related effects on monoazo reactive dyes derived from H-acid, g-acid, and related naphthalene sulfonic acids, Dyes Pigm. 60 (2004) 23-48.[4] T. Hihara, Y. Okada, Z. Morita, Relationship between photochemical properties and colourfastness due to light-related effects on monoazo reactive dyes derived from H-acid, g-acid, and related naphthalene sulfonic acids, Dyes Pigm. 60 (2004) 23-48.

    5. [5] P. Aranyosi, Z. Csepregi, I. Rusznák, et al., The light stability of azo dyes and azo dyeings. Ⅲ. The effect of artificial perspiration on the light stability of reactive and non-reactive derivatives of two selected azo chromophores in aqueous solution, Dyes Pigm. 37 (1998) 33-45.[5] P. Aranyosi, Z. Csepregi, I. Rusznák, et al., The light stability of azo dyes and azo dyeings. Ⅲ. The effect of artificial perspiration on the light stability of reactive and non-reactive derivatives of two selected azo chromophores in aqueous solution, Dyes Pigm. 37 (1998) 33-45.

    6. [6] Y.Q. Yang, V. Naarani, Improvement of the lightfastness of reactive inkjet printed cotton, Dyes Pigm. 74 (2007) 154-160.[6] Y.Q. Yang, V. Naarani, Improvement of the lightfastness of reactive inkjet printed cotton, Dyes Pigm. 74 (2007) 154-160.

    7. [7] D. Cristea, G. Vilarem, Improving light fastness of natural dyes on cotton yarn, Dyes Pigm. 70 (2006) 238-245.[7] D. Cristea, G. Vilarem, Improving light fastness of natural dyes on cotton yarn, Dyes Pigm. 70 (2006) 238-245.

    8. [8] J.J. Lee, H.H. Lee, S.I. Eom, et al., UV absorber aftertreatment to improve lightfastness of natural dyes on protein fibres, Color. Technol. 117 (2001) 134-138.[8] J.J. Lee, H.H. Lee, S.I. Eom, et al., UV absorber aftertreatment to improve lightfastness of natural dyes on protein fibres, Color. Technol. 117 (2001) 134-138.

    9. [9] T. Feczkó, M. Kovács, B. Voncina, Improvement of fatigue resistance of spirooxazine in ethyl cellulose and poly(methylmethacrylate) nanoparticles using a hindered amine light stabilizer, J. Photochem. Photobiol. A: Chem. 247 (2012) 1-7.[9] T. Feczkó, M. Kovács, B. Voncina, Improvement of fatigue resistance of spirooxazine in ethyl cellulose and poly(methylmethacrylate) nanoparticles using a hindered amine light stabilizer, J. Photochem. Photobiol. A: Chem. 247 (2012) 1-7.

    10. [10] H.S. Jia, H.L. Wang, W.X. Chen, The combination effect of hindered amine light stabilizers with UV absorbers on the radiation resistance of polypropylene, Radiat. Phys. Chem. 76 (2007) 1179-1188.[10] H.S. Jia, H.L. Wang, W.X. Chen, The combination effect of hindered amine light stabilizers with UV absorbers on the radiation resistance of polypropylene, Radiat. Phys. Chem. 76 (2007) 1179-1188.

    11. [11] J. Akrman, J. Prikryl, Application of benzotriazole reactive UV absorbers to cellulose and determining sun protection of treated fabric spectrophotometrically, J. Appl. Polym. Sci. 108 (2008) 334-341.[11] J. Akrman, J. Prikryl, Application of benzotriazole reactive UV absorbers to cellulose and determining sun protection of treated fabric spectrophotometrically, J. Appl. Polym. Sci. 108 (2008) 334-341.

    12. [12] W. Ma, X. Jiang, Y. Liu, B.T. Tang, S.F. Zhang, Synthesis of a novel water-soluble polymeric UV-absorber for cotton, Chin. Chem. Lett. 22 (2011) 1489-1491.[12] W. Ma, X. Jiang, Y. Liu, B.T. Tang, S.F. Zhang, Synthesis of a novel water-soluble polymeric UV-absorber for cotton, Chin. Chem. Lett. 22 (2011) 1489-1491.

    13. [13] Z.Y. Hu, S.F. Zhang, J.Z. Yang, et al., Some properties of aqueous-solutions of poly(vinylamine chloride), J. Appl. Polym. Sci. 89 (2003) 3889-3893.[13] Z.Y. Hu, S.F. Zhang, J.Z. Yang, et al., Some properties of aqueous-solutions of poly(vinylamine chloride), J. Appl. Polym. Sci. 89 (2003) 3889-3893.

    14. [14] X.P. Lei, D.M. Lewis, Y.N. Wang, Level fast dyeing of wool with nucleophilic aminoalkyl dyes and crosslinking agents. Part 2: using bifunctional crosslinking agents, J. Soc. Dyers Colour. 111 (1995) 385-390.[14] X.P. Lei, D.M. Lewis, Y.N. Wang, Level fast dyeing of wool with nucleophilic aminoalkyl dyes and crosslinking agents. Part 2: using bifunctional crosslinking agents, J. Soc. Dyers Colour. 111 (1995) 385-390.

  • 加载中
计量
  • PDF下载量:  431
  • 文章访问数:  2828
  • HTML全文浏览量:  64
文章相关
  • 收稿日期:  2012-09-26
  • 网络出版日期:  2013-01-01
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章