Citation:
An LIU, Zhan Zhu LIU, Zhong Mei ZOU, Shi Zhi CHEN, Li Zhen XU, Shi Lin YANG. Enantioselective Total Synthesis of the (+) Antipode of Zeylenone[J]. Chinese Chemical Letters,
;2004, 15(12): 1433-1436.
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Starting from shikimic acid, the total synthesis of zeylenone was studied. The product was proved to be the (+)antipode of zeylenone through analysis and comparison of their respective spectra (including NMR, MS, IR and CD) and optical data. The absolute configuration of the natural product was thus determined to be (1 S,2S,3R).
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Keywords:
- Zeylenone,
- absolute configuration,
- shikimic acid,
- total synthesis,
- enantiomer
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