Citation: Le-Chen Chen, Shan Lei, Mo-Zhen Wang, Jun Yang, Xue-Wu Ge. Fabrication of macroporous polystyrene/graphene oxide composite monolith and its adsorption property for tetracycline[J]. Chinese Chemical Letters, ;2016, 27(4): 511-517. shu

Fabrication of macroporous polystyrene/graphene oxide composite monolith and its adsorption property for tetracycline

a The USTC-Anhui Tobacco Joint Laboratory of Tobacco Chemistry, CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China;
b The USTC-Anhui Tobacco Joint Laboratory of Tobacco Chemistry, Research Center of Tobacco and Health, University of Science and Technology of China, Hefei 230052, China

Received Date: 4 January 2016
Revised Date: 25 January 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 51073146, 51103143, 51173175, 51473152, and 51573174), the Fundamental Research Funds for the Central Universities (Nos. WK2060200012 and WK3450000001), and the Foundation of Anhui Key Laboratory of Tobacco Chemistry (China Tobacco Anhui Industrial Co., Ltd.) (No. 2014126).

Macroporous polystyrene microsphere/graphene oxide (PS/GO) composite monolith was first prepared using Pickering emulsion droplets as the soft template. The Pickering emulsion was stabilized by PS/GO composite particles in-situ formed in an acidic water phase. With the evaporation of water and the oil phase (octane), the Pickering emulsion droplets agglomerated and combined with each other, forming a three-dimensional macroporous PS/GO composite matrix with excellent mechanical strength. The size of the macrospores ranged from 4 μm to 20 μm. The macroporous PS/GO composite monolith exhibited high adsorption capacity for tetracycline (TC) in an aqueous solution at pH 4-6. The maximum adsorption capacity reached 197.9 mg g^-1 at pH 6. The adsorption behaviour of TC fitted well with the Langmuir model and pseudo-second-order kinetic model. This work offers a simple and efficient approach to fabricate macroporous GO-based monolith with high strength and adsorption ability for organic pollutants.
- Graphene oxide,
- Polystyrene microsphere,
- Macroporousm,
- Adsorption,
- Tetracycline
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
1. [1]
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2. [2]
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4. [4]
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