Citation: Bin Wang, Hui Yang, Ya-Bo Xie, Yi-Bo Dou, Min-Jian Zhao, Jian-Rong Li. Controlling structural topology of metal-organic frameworks with a desymmetric 4-connected ligand through the design of metal-containing nodes[J]. Chinese Chemical Letters, ;2016, 27(4): 502-506. shu

Controlling structural topology of metal-organic frameworks with a desymmetric 4-connected ligand through the design of metal-containing nodes

Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

Received Date: 9 September 2015
Revised Date: 22 December 2015

Fund Project: This work was financially supported by the NSFC (Nos. 21322601, 21271015, 21406006, andU1407119) and Program for New Century Excellent Talents in University (No. NCET-13-0647).

Two new metal-organic frameworks (MOFs),[Cu₂(H₂O)₂(BCPIA)] (BUT-20) and (Me₂NH₂)[In(BCPIA)] (BUT-21) were designed and synthesized through the solvothermal reaction between a newly created desymmetric 4-connected ligand, 5-(2, 6-bis(4-carboxyphenyl)pyridin-4-yl)isophthalic acid (H₄BCPIA) and Cu(NO3)2·2.5H₂O or In(NO₃)₃·5H₂O, respectively, and characterized by single-crystal and powder Xray diffraction, thermogravimetric analysis, infrared spectroscopy, and elemental analysis. The two MOFs have three-dimensional structures, in which both the BCPIA4-ligand and metal-containing entities, Cu₂(COO)₄(H₂O)₂ and In(COO)₄ act as 4-connected nodes. However, different linkage configurations of the two metal-containing nodes, quadrilateral Cu₂(COO)₄(H₂O)₂ and tetrahedral In(COO)₄, lead to distinct structural networks of BUT-20 and -21, with Nbo and Unc topologies, respectively.
- Metal-organic frameworks (MOFs),
- Design and synthesis,
- Crystal structure,
- Tuned topological network
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