Citation: Ting Wang, Qing-Hui Liu, Ying Gao, Xiu-Yun Yang, Weiting Yang, Song Dang, Zhong-Ming Sun. A multi-responsive luminescent sensor towards Fe³⁺ and acetone based on a Cd-containing metal-organic framework[J]. Chinese Chemical Letters, ;2016, 27(4): 497-501. shu

A multi-responsive luminescent sensor towards Fe³⁺ and acetone based on a Cd-containing metal-organic framework

a Changchun University of Science & Technology, School of Chemistry and Environmental Engineering, Changchun 130012, China;
b State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
c College of Physics, Jilin University, Changchun 130012, China

Received Date: 11 September 2015
Revised Date: 27 November 2015

Fund Project: This work was supported by National Natural Science Foundation of China (Nos. 21171162, 21471144), Jilin Province Youth Foundation ([15TD$DIF]No. 20130522132JH), Jilin Province Natural Science Foundation ([15TD$DIF]No. 20150101181JC), Changchun Science and Technology Plan ([15TD$DIF]No. 2013059).

A Cd-containing metal-organic framework (CdL), formula as {[Cd₃(L)₂(H₂O)₆]·1.5DMF}, has been synthesized under solvothermal condition by the reaction of 4, 4', 4"-(methylsilanetriyl)tribenzoic acid (H₃L) and Cd²⁺ ion. Single-crystal X-ray diffraction reveals that CdL displays a three-dimensional framework with 2-fold interpenetration and DMF molecules locate in the void space of the channels. A topological analysis of the framework indicates CdL is a 3, 4-connected pto net. The photoluminescence properties of CdL are systematically studied in detail. Impressively, CdL shows excellent detection performance towards Fe³⁺ ion and acetone in the sensing experiments, which undoubtedly demonstrates the great potential of CdL as a highly selective multi-responsive luminescent sensor for the detection of organic solvents and metal ions.
- Metal-organic framework,
- Fluorescent probe,
- Multi-responsive sensor,
- Luminescent quenching
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通讯作者: 陈斌, bchen63@163.com

A multi-responsive luminescent sensor towards Fe³⁺ and acetone based on a Cd-containing metal-organic framework