Citation: Ji-Min Yang, Zhao-Peng Qi, Yan-Shang Kang, Qing Liu, Wei-Yin Sun. Shape-controlled synthesis and photocatalytic activity of In₂O₃ nanostructures derived from coordination polymer precursors[J]. Chinese Chemical Letters, ;2016, 27(4): 492-496. shu

Shape-controlled synthesis and photocatalytic activity of In₂O₃ nanostructures derived from coordination polymer precursors

a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China;
b School of Chemistry & Chemical Engineering, Linyi University, Linyi 276005, China

Received Date: 8 December 2015
Revised Date: 28 December 2015

Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21331002).

In(BTC)(phen)(H₂O) nanocrystals with controllable morphology and size were successfully obtained by solvothermal method. Hierarchical straw-sheaf-like architectures, nanorods and elongated hexagons have been synthesized by varying the volume ratio of DMF:H₂O:C₂H₅OH. Phase-pure In₂O₃ nanocrystals were obtained by the calcination of the precursors without significant alteration of themorphology. The products were characterized by PXRD, SEM, TEM, TGA, IR and gas adsorption measurements. The photocatalytic effect was investigated for the In₂O₃ nanocrystals with different morphology on the degradation of rhodamine B (RhB) and it was found that the nanorods exhibited the best photocatalytic activity, which shows the degradation efficiency of 94% for 8 h. The results showed that the photocatalytic activity increased with the increase of BET surface area and pore volume.
- In(BTC)(phen)(H₂O),
- Morphology,
- In₂O₃,
- Photocatalysis,
- Rhodamine B
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Shape-controlled synthesis and photocatalytic activity of In2O3 nanostructures derived from coordination polymer precursors

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通讯作者: 陈斌, bchen63@163.com

Shape-controlled synthesis and photocatalytic activity of In₂O₃ nanostructures derived from coordination polymer precursors