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Citation: Chen Ruyu, Zhang Chengxiang, Feng Kesheng, Cheng Muru. Synthesis and Herbicidal Activity of 4-Aryloxy-4-Oxo-1, 3, 4-Diazaphospholidin-2-Thione[J]. Chinese Journal of Applied Chemistry, ;1996, 13(5): 100-102. shu

Synthesis and Herbicidal Activity of 4-Aryloxy-4-Oxo-1, 3, 4-Diazaphospholidin-2-Thione

1.
Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071

Received Date: 1 December 1995
Available Online: 6 June 1996

Phenylthiourea was reacted with trichlorophosphine and aldehydes(ketones) to produce 3-phenyl-4-chloro-4-oxo-1,3,4-diazaphospholidin-2-thione(Ⅰ). The compounds Ⅰ were then reacted with phenols to produce the titled compounds Ⅲ. The structures of compounds Ⅲ were comfirmed by ¹H NMR,³¹P NMR and elemental analysis. The biological tests found that compounds Ⅲ have good selective herbicidal activities.
- diazaphospholidinthione,
- phenol,
- herbicidal activity
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