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Citation: Chen Ruyu, He Liangnian, Yang Xiufeng. Synthesis and Herbicidal Activity of 1-(p-Toluenesulfonyl)-2-Phenoxy-3-Aryl-4-Phenyl-1, 4, 2-Diazaphospholidin-5-one-2-Oxides[J]. Chinese Journal of Applied Chemistry, ;1996, 13(5): 29-32. shu

Synthesis and Herbicidal Activity of 1-(p-Toluenesulfonyl)-2-Phenoxy-3-Aryl-4-Phenyl-1, 4, 2-Diazaphospholidin-5-one-2-Oxides

1.
Institute of Elemento-Organic Chemistry, Nankai University, The National Key Laboratory of Elemento-Organic Chemistry, Tianjin 300071

Received Date: 28 December 1995
Available Online: 17 May 1996
Fund Project:

A series of 1-(p-toluenesulfonyl)-2-phenoxy-3-aryl-4-phenyl-1,4,2-diazaphospholidin-5-one-2-oxides (2) has been synthesized by the. Mannich-type reaction of 1-phenyl-3-(ptoluenesulfonyl) urea(1), substituted benzaldehydes and triphenyl phosphite in anhydrous toluene. The side reactions were discussed. The structures of new compounds were characterized by ¹H NMR, ³¹P NMR, elemental analysis, MS and IR spectra. The results of preliminary bioassay showed that the compound 2 possesses good selective herbicidal activity against rape.
- diazaphospholidin-one,
- synthesis,
- herbicidal activity
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