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Citation: Yu Xinwu, Zhang Shuyun, Zhang Jiyu, Wang Enbo, Zhan Ruiyun, Liu Guizhen. Synthesis, Characterization and Catalytic Activity of New Layered Microporous Material-FeW₁₁NiO₃₉Pillared Anion Clay[J]. Chinese Journal of Applied Chemistry, ;1996, 13(4): 17-20. shu

Synthesis, Characterization and Catalytic Activity of New Layered Microporous Material-FeW₁₁NiO₃₉Pillared Anion Clay

1.
1. Department of Chemistry, Northeast Normal University, Changchun 130024;
2.
2. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130024

Received Date: 21 August 1995
Available Online: 30 December 1995
Fund Project:

Layered double hydroxides pillared by tungstoferrate heteropolyanion with substituted transition metal Ni, ZnAl-FeW₁₁Ni, has been synthesized by means of hydrothermal ion exchange method. Powder X-ray diffraction shows that the anionic clay precursor possesses a regular layered structure and a good crystallinity, and the pillared derivative has 2θ of 4.96° and gallery height of 1.325 nm. IR spectra indicate that the vibrational frequency and band shape of heteropolyanion existing in the layered regions of anionic clay are similar to those of the authentic heteropoly salt. So we can draw the conclusion that the Keggin structure of the gallery heteropoly anions is maintained. ESR results indicate that the heteropolyainons are of ordered arrangement in layered clay region.Tests show that the new pillared compound has a higher catalytic activity than that of anionic clay and heteronoly salts for dioctyl phthalate synthesis.
- microporous material,
- anionic clay,
- FeW₁₁NiO₃₉,
- heteropoly compound,
- transition metal,
- catalytic activity
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Synthesis, Characterization and Catalytic Activity of New Layered Microporous Material-FeW11NiO39Pillared Anion Clay

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Synthesis, Characterization and Catalytic Activity of New Layered Microporous Material-FeW₁₁NiO₃₉Pillared Anion Clay