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Citation: Zhou Chenghe, Yuan Deqi, Xie Rugang. Selective Synthesis of Phenylglycine in the Presence of Phase Transfer Catalyst-β-Cyclodextrin Binary System[J]. Chinese Journal of Applied Chemistry, ;1996, 13(3): 46-49. shu

Selective Synthesis of Phenylglycine in the Presence of Phase Transfer Catalyst-β-Cyclodextrin Binary System

1.
Department of Chemistry, Sichuan University, Chengdu 610064

Received Date: 26 September 1995
Available Online: 22 January 1996
Fund Project:

A one-pot selective synthesis of phenylglycine with high yield from benzaldehyde, chloroform,potassium hydroxide and ammonia in the presence of phase-transfer catalyst (PTC)and β-cyclodextrin(β-CD)binary catalyst system has been studied.Results obtained are far superior to that of other similar methods.The data show that PTC β-CD is a more efficient catalyst than either PTC or β-CD alone,and both cationic and nonionie PTC-β-CD can enhance the production of phenylglycine with good yields and selectivities.A preliminary mechanism is also discussed.
- phenylglycine,
- β-eyclodextrin,
- phase-transfer catalyst,
- selectivity,
- synthesis
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