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Citation: Xu Li, Wu Guoqing. Synthesis and Crystal Structure of KSmLaF₆[J]. Chinese Journal of Applied Chemistry, ;1997, 14(4): 74-76. shu

Synthesis and Crystal Structure of KSmLaF₆

Xu Li ¹ ,
Wu Guoqing ²

1.
1. Department of Chemistry, Zhejiang University, Hangzhou 310027;
2.
2. Department of Chemistry, Beijing Normal University, Beijing

Received Date: 30 November 1996
Available Online: 3 June 1997
Fund Project:

KSmLaF₆ was synthesized by reducing Sm_0.5La_0.5F₃ with potassium vapor at 300℃ or 420℃. The new compound has two phases:the low-temperature phase is trigonal crystal system with lattice parameters a=0.6493(2) nm, c=0.3777(1) nm, c/a=0.582, Z=1, sapce group P3; and the high-temperature phase is cubic crystal system with lattice parameters a=0.5873(3) nm, Z=4/3, space group Fm3m.
- samarium(Ⅱ),
- fluoride,
- synthesis,
- crystal structure
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Synthesis and Crystal Structure of KSmLaF₆