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Citation: Xu Pianpian, Gao Jingxing, Huang Peiqiang, Wang Huilin, Wang Wenguo, Cheng Shouzheng. Synthesis and Hydrogenation Activity of Diiminodiphosphine Ruthenium Complex RuCl₂P₂N₂[J]. Chinese Journal of Applied Chemistry, ;1997, 14(3): 58-61. shu

Synthesis and Hydrogenation Activity of Diiminodiphosphine Ruthenium Complex RuCl₂P₂N₂

1.
1. Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surface, Institute of Physical Chemistry, Xiamen University, Xiamen 361005;
2.
2. Department of Chemistry, Fujian Normal University, Fuzhou

Received Date: 6 November 1996
Available Online: 5 March 1997
Fund Project:

The trans form of the title complex was synthesized in high yield by interaction of equimole RuCl₂(Ph₃P)₄ or RuCl₂(DMSO)₄ (DMSO=dimethylsulfoxide) with P₂N₂ (i.e.=N,N'-bis[o-(diphenylphosphine-benzylidene)] ethylene diamine) in refluxing toluene. The complex has been investigated as catalyst for selective hydrogenation of T,U-unsaturated acids and some functionalized olefins. The hydrogenation catalytic activity was observed as follows:styrene > acrylic acid > benzaldehyde > salicyl aldehyde > cyclohexanone > furfural > methylacrylic acid》acetophenone. The effect of addition of NH₄PF₆ or AgNO₃ as promotor has also been studied.
- diiminodiphosphine ligand,
- ruthenium complex,
- synthesis,
- hydrogenation,
- catalytic activity
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Synthesis and Hydrogenation Activity of Diiminodiphosphine Ruthenium Complex RuCl2P2N2

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Synthesis and Hydrogenation Activity of Diiminodiphosphine Ruthenium Complex RuCl₂P₂N₂