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Citation: Su Xiaodi, Liu Zhaolin, Zhu Min, Shen Hanxi. Enhanced Effect of Enhancing Agents on the Oxidation Reaction Catalyzed by Mimetic Horseradish Peroxidase——Fe-TPPS₄-4-AAP-Phenol-H₂O₂ System[J]. Chinese Journal of Applied Chemistry, ;1997, 14(3): 33-36. shu

Enhanced Effect of Enhancing Agents on the Oxidation Reaction Catalyzed by Mimetic Horseradish Peroxidase——Fe-TPPS₄-4-AAP-Phenol-H₂O₂ System

1.
1. Department of Applied Chemistry, Tianjin University, Tianjin 300071;
2.
2. Department of Chemistry, Nankai University, Tianjin 300071

Received Date: 27 August 1996
Available Online: 21 January 1997

The enhanced effect of U-cyclodextrin(U-CD) or surfactants on the oxidation reaction of H₂O₂ with 4-aminoantipyrine and phenol, using iron-(4-sulphophenyl) porphine (Fe-TPPS₄) as catalyst has been studied. It is indicated that the initial rate and sensitivity of this color reaction are increased with the added amount of U-CD or sodium dodecylbenzene sulfate(SDBS). A sensitive method for the determination of H₂O₂ in the presence of U-CD has been developed. Trace amount of SDBS can be determined based on the linear relationship between the increment of the reaction rate and the concentration of the surfactant.
- U-cyclodextrin,
- surfactant,
- mimetic enzyme,
- H₂O₂ determination,
- enhanced spectrophotometry
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Enhanced Effect of Enhancing Agents on the Oxidation Reaction Catalyzed by Mimetic Horseradish Peroxidase——Fe-TPPS4-4-AAP-Phenol-H2O2 System

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Enhanced Effect of Enhancing Agents on the Oxidation Reaction Catalyzed by Mimetic Horseradish Peroxidase——Fe-TPPS₄-4-AAP-Phenol-H₂O₂ System