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Citation: Hu Xiance, Liu Wanyu, Jiang Weiguo, Zong Huijuan. PREPARATION OF SINGLE-ION POLYMER CONDUCTOR——COMBLIKE POLYMERS WITH CARBOXYLATE GROUPS[J]. Chinese Journal of Applied Chemistry, ;1993, 10(6): 14-18. shu

PREPARATION OF SINGLE-ION POLYMER CONDUCTOR——COMBLIKE POLYMERS WITH CARBOXYLATE GROUPS

1.
Department of Materials Science and Engineering, University of Science and Technology of China, 230026 Hefei

Received Date: 9 December 1992
Available Online: 4 June 1993

The single-ion conducting polymer electrolytes with carboxylate groups immobilized on the backbones have been synthesized by alcoholysis of maleic anhydride-styrene or maleic anhydride-vinyl acetate copolymers with PEO monomethyl ether. The plasticized comblike polymeric lithium salt film showed conductivity up to 10^-6 S/cm at room temperature. The effects of polymer structure, cation radius, plasticizer, temperature and frequency on the conductivity were investigated.
- maleic anhydride-vinyl acetate copolymer,
- maleic anhydride-styrene copolymer,
- polymer single-ion conductor,
- preparation
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