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Citation: Ping Xuezhen, Qiu Xingyu. CATALYTIC ESTER INTERCHANGE OF 1,1'-BISNAPHTHOL-4,4'-DIACETATE AND DI(2-ETHYLHEXYL)CARBONATE[J]. Chinese Journal of Applied Chemistry, ;1993, 10(1): 71-73. shu

CATALYTIC ESTER INTERCHANGE OF 1,1'-BISNAPHTHOL-4,4'-DIACETATE AND DI(2-ETHYLHEXYL)CARBONATE

Ping Xuezhen ,
Qiu Xingyu

1.
Department of Chemistry, Liaoning University, 110036 Shenyang

Received Date: 19 December 1991
Available Online: 19 May 1992

The ester interchange of 1,1'-bisnaphthol-4,4'-diacetate and di (2-ethylhexyl) carbonate using various metal compounds as catalysts has been investigated. The relative reactivity of the catalysts was compared from the kinetic data measured by determining the amount of 2-ethylhexyl acetate released during the reaction. GC/MS analysis showed that the poly (1,1'-bisnaphthol carbonate), 2-ethylhexyl acetate, heptanone,octene and acetic acid (acetic anhydride) were formed during the ester interchange.
- 1,1'-bisnaphthol-4,4'-diacetate,
- di(2-ethylhexyl)carbonate,
- ester interchange,
- metal catalyst
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