Citation:
XIA Xiao-Dong, YI Ping-Gui, YU Xian-Yong. The Release of Metal-Enhanced Fluorescence Ag@SiO2 Nanocomposites for Glucose Detection[J]. Chinese Journal of Applied Chemistry,
;2009, 26(6): 1456-1460.
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Ag@SiO2 and rhodamine-doped Ag@SiO2 nanocomposites were prepared.Rhodamine fluorescence intensity was enhanced by a factor of 4.7 due to metal-enhanced fluorescence.The Ag core was easily oxidized by H2O2,enhancing the fluorescence release of rhodamine.Glucose oxidase was immobilized on the layer of SiO2 shell by chemical cross linked cluster.A novel method to detect glucose was developed based on metal-enhanced fluorescence in a concentration range of 0.2~6.8 mmol/L with a detection limit of 0.06 mmol/L.Speedy detection response was obtained upon the fast oxidation of Ag core by H2O2.
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