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Citation: ZHAO Yan, YAO Jin-Shui, SUN Xi-Jun. Preparation of Polysiloxane Chiral Stationary Phase Grafted with Ester Monomer[J]. Chinese Journal of Applied Chemistry, ;2009, 26(6): 1395-1398. shu

Preparation of Polysiloxane Chiral Stationary Phase Grafted with Ester Monomer

1.
College of Material Science and Engineering, Shandong Institute of Light Industry, Ji'nan 250353

Corresponding author: YAO Jin-Shui,
Received Date: 22 November 2008
Available Online: 10 March 2009
Fund Project: 国家自然科学基金资助项目(20374035) (20374035)山东省自然科学基金资助项目(Y2006F42) (Y2006F42)教育部新世纪人才计划(NCET-07-0521) (NCET-07-0521)

With methyl-S-(-)-lactate,S-(-)-α phenylethyl alcohol,(S)-(+)-2-butanol as the chiral pool,new chiral unsaturated esters were synthesized under the catalysis of N,N'-dicyclohexyl carbodimide(DCC) and 4-dimethylaminopyridines.The products were characterized by means of infrared,NMR and elemental analysis.A chiral stationary phase was obtained by grafting these monomers to polysiloxane.
- asymmetric synthesis,
- ester chiral monomer,
- chiral stationary phase,
- polysiloxane
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