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Citation: YANG Ze-Heng, GUI Bin, ZHOU Chen-Xu, LIU Teng. Preparation of ZnMn₂O₄ Nano-catalyst and Its Application in Synthesis of n-Butyl Acetate[J]. Chinese Journal of Applied Chemistry, ;2009, 26(11): 1315-1319. shu

Preparation of ZnMn₂O₄ Nano-catalyst and Its Application in Synthesis of n-Butyl Acetate

1.
College of Chemical Engineering, Hefei University of Technology and Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009

Corresponding author: YANG Ze-Heng,
Received Date: 23 October 2008
Available Online: 15 February 2009
Fund Project: 国家自然科学基金(20576024,20876031) (20576024,20876031)安徽省自然科学基金(070414165)资助项目 (070414165)

A zinc manganese oxide nano-catalyst was synthesized by a co-precipitation method.X-ray diffraction(XRD) and transmission electron microscopy(TEM) results indicate that the sample can be indexed to tetragonal ZnMn₂O₄ and the particle size ranges from 20 to 50 nm.The obtained ZnMn₂O₄ nanoparticles were used as a catalyst for the esterification reaction between acetic acid and n-butanol.The experimental results show that ZnMn₂O₄ nanoparticles had a high catalytic activity on the synthesis of n-butyl acetate.The influential factors including catalyst calcination temperature,acid-to-alcohol molar ratio,dosage of the catalyst and reaction time on the yield of n-butyl acetate were also investigated,and the maximal esterification rate of up to 92.53% was achieved under the following conditions: catalyst calcination temperature=300 ℃,n(acid):n(alcohol)=1.8:1,the dosage of the ZnMn₂O₄ catalyst is 0.3%(in total mass of reactants),reaction time is 4 h and esterification reaction temperature is 120 ℃.
- co-precipitation,
- ZnMn₂O₄,
- catalysis,
- n-butyl acetate
1. [1]
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2. [2]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
3. [3]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
4. [4]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
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  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
12. [12]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . 废塑料促进S型NiCr₂O₄/孪晶Cd_0.5Zn_0.5S同质异质结光催化产氢. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-. doi: 10.1016/j.actphy.2025.100068
13. [13]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . S型ZnO/CdIn₂S₄光催化剂制备H₂O₂偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
14. [14]
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15. [15]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
16. [16]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
17. [17]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
18. [18]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
19. [19]
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20. [20]
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Preparation of ZnMn₂O₄ Nano-catalyst and Its Application in Synthesis of n-Butyl Acetate