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Citation: XU Ye-Wei, ZHU Fang-Hua, ZHANG Hai-Lian, WANG Peng, ZHANG Lin. Synthesis and Characterization of Soluble Perylene Diimide Light-emitting Materials[J]. Chinese Journal of Applied Chemistry, ;2009, 26(11): 1269-1272. shu

Synthesis and Characterization of Soluble Perylene Diimide Light-emitting Materials

1.
a School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang;
2.
b Research Center of Laser Fusion, Chinese Academy of Engineering Physics, Mianyang 621900

Corresponding author: ZHANG Lin,
Received Date: 3 November 2008
Available Online: 17 March 2009
Fund Project: 中国工程物理研究院高温高密度等离子体物理国防科技重点实验室基金(9140C6806040611)资助项目 (9140C6806040611)

Perylene derivatives PeryBr2,DD-PeryBr₂ and DD-PeryBp₂ were synthesized from perylene-3,4,9,10-tetracarboxylic acid bisanhydride and characterized by UV-Vis,FT-IR,¹H NMR,MS,TGA and fluore-scence spectroscopy measurements.The result shows that DD-PeryBp2 is highly soluble in conventional solvents such as toluene,chloroform and THF.The UV-Vis maximal absorption and fluorescence spectroscopy maximal emission of DD-PeryBp₂ are at 548 nm and 576 nm,respectively.TG measurements show that perylene diimides possess good thermal stability and the temperature at which 5% mass loss is observed in nitrogen is 433 ℃.
- perylene diimides,
- solubility,
- thermal stability,
- light-emitting material
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