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Citation: HUANG Xue-Yuan, GUO Jian-Ping, SHEN Jia-Chun, CHEN Xiao-Hua, YIN Du-Lin. Gel Polymer Electrolytes Prepared from Vinyl Monomers in [BMIM]Cl-ZnCl₂ and Aprotic Solvents[J]. Chinese Journal of Applied Chemistry, ;2009, 26(10): 1139-1143. shu

Gel Polymer Electrolytes Prepared from Vinyl Monomers in [BMIM]Cl-ZnCl₂ and Aprotic Solvents

1.
College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081

Corresponding author: GUO Jian-Ping,
Received Date: 24 October 2008
Available Online: 20 December 2008
Fund Project: 湖南省科技计划(2006JT2009)资助项目 (2006JT2009)

Gel polymer electrolytes with ionic liquid [BMIM]Cl-ZnCl₂ and an aprotic solvent were prepared via in situ free radical polymerization from vinyl monomers MA,MMA or HEMA as matrix and studied. The structure and properities of the products were studied by means of FTIR,AC,and TG. The interactions and structure changes of the composites were investigated by FTIR. The combination of a Lewis acid ionic liquid,[BMIM]Cl-ZnCl₂ with aprotic solvent PC or DMC strongly increased the ionic conductivity in comparison with the neat ionic liquid,which showed a highly ionic conductivity of up to 2.83×10^-3 S/cm at room temperature. And the activation energies of ions were calculated according to VTF equation. The gel polymer electrolytes exhibited high decomposition temperatures of above 275 ℃.
- vinyl monomer,
- ionic liquid,
- aprotic solvent,
- ionic conductivity,
- thermal stability,
- in situ radical polymerization
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沈阳化工大学材料科学与工程学院沈阳 110142

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Gel Polymer Electrolytes Prepared from Vinyl Monomers in [BMIM]Cl-ZnCl2 and Aprotic Solvents

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Gel Polymer Electrolytes Prepared from Vinyl Monomers in [BMIM]Cl-ZnCl₂ and Aprotic Solvents