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Citation: ZHOU Hong-Ping, SONG Wen-Li, ZHU Chen-Hao, WANG Yan, YIN Jian-Hui, KONG Lin, WU Zhi-Chao, WU Jie-Ying. Synthesis,Characterization and Optical Properties of a Novel Carbazole Carboxylate Derivative[J]. Chinese Journal of Applied Chemistry, ;2009, 26(6): 657-661. shu

Synthesis,Characterization and Optical Properties of a Novel Carbazole Carboxylate Derivative

1.
College of Chemistry and Chemical Engineering, Anhui University Anhui Key Laboratory of Functional Inroganic Materials Chemistry, Hefei 230039

Corresponding author: ZHOU Hong-Ping,
Received Date: 21 May 2008
Available Online: 28 August 2008
Fund Project: 国家自然科学基金(50703001,20771001) (50703001,20771001)安徽省高校青年教师科研资助计划(2007jq1019) (2007jq1019)安徽省高校省级科技创新团队基金(2006KJ007TD)资助项目 (2006KJ007TD)

A new carbazole derivative,9-isooctyl-3,6-carbazole dicrylic acid,was synthesized and characte-rized by ¹H NMR,¹³C NMR,IR and MS.UV,one-photon excited fluorescence spectra and solid fluorescence of the intermediate and title product in different polar solvents were investigated.The results show that the target product had good UV absorption characteristic and single-photon fluorescence effect at 300~500 nm with increasing polarity of the solvent.With the ethanol solution of Rhodamine B as a reference,we calculated the quantum yields of the target product in different solvents to be more than 0.19.So the compound could be a potential luminescent material.
- carbazole,
- crylic acid,
- Heck reaction
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