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Citation: WANG Rui-Fang, OU Lai-Liang, SHI Zuo-Qing. Chromatographic Separation of Camptothecine and Vincoside-Lactam by Resins with Nanometer Micropores[J]. Chinese Journal of Applied Chemistry, ;2009, 26(5): 593-596. shu

Chromatographic Separation of Camptothecine and Vincoside-Lactam by Resins with Nanometer Micropores

1.
a College of Bio-engineering, Jimei University, Xiamen 361021;
2.
b Key Laboratory of Bioactive Materials, Ministry of Education, Institute of Molecular Biology, Nankai University, Tianjin 300071

Corresponding author: WANG Rui-Fang,
Received Date: 30 April 2008
Available Online: 27 June 2008
Fund Project: 国家自然科学基金资助项目(20174017) (20174017)福建省青年人才资助项目(2006F3094) (2006F3094)

The performance of adsorption and chromatographic separation of camptothecine and vincoside-lactam by polymeric resins with different nanometer pores were studied.The static adsorption results show the adsorption capacity of vincoside-lactam is related to the specific area of the resin.The adsorption capacity of gel post-crosslinked resin with a specific area of 1 100 m²/g is larger than that of other two adsorbents.The adsorption discrepancy of Rf8 for camptothecine and vincoside-lactam was the most and the separation factor reached to 2.01.The dynamic desorption results show that macroporous post-crosslinked resin Rf8 with micropore and macropore structures and carbonyl group can separate camptothecine and vincoside-lactam effectively via chromatography,but macroporous resin ADS-5 and gel post-crosslinked resin X1 can not.Such effective chromatographic separation of camptothecine and vincoside-lactam with resin Rf8 is ascribed to the surface character and hole structure of the resin.
- macroporous resin,
- gel post-crosslinked resin,
- macroporous post-crosslinked resin,
- camptothecine,
- vincoside-lactam,
- chromatographic separation
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