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Citation: YUAN Ai-Ping, HUANG Yu-Long, TANG Yan-Xia, WANG Jing-Ling, QIN Ran. Fast Determination of As,Hg,Se,Bi and Sn in Antimony Concentrate by Hydride Generation Atomic Fluorescence Spectrometry[J]. Chinese Journal of Applied Chemistry, ;2009, 26(2): 229-233. shu

Fast Determination of As,Hg,Se,Bi and Sn in Antimony Concentrate by Hydride Generation Atomic Fluorescence Spectrometry

1.
Guangxi Entry-Exit Inspection and Quarantine Bureau, Nanning 530028

Corresponding author: YUAN Ai-Ping,
Received Date: 29 December 2007
Available Online: 29 April 2008
Fund Project: 国家质量监督检验检疫总局科研资助项目(2004IK079) (2004IK079)

A method for the determination of As,Hg,Se,Bi and Sn in antimony concentrates by hydride generation atomic fluorescence spectrometry(HG-AFS) was established.The effects of dissolving sample and concomitant ions were studied.The sample can be completely soluble in aqua regia.Trace arsenic,mercury,selenium,bismuth and tin of real samples were determinated without chemical seperation in the medium with different acidities by adding tartaric acid to inhibit the hydrolysis of antimony.The detection limits were 0.22 μg/L,0.002 μg/L,0.18 μg/L,0.11 μg/L and 0.50 μg/L for As,Hg,Se,Bi and Sn,respectively.The recoveries of the 5 elements were from 88% to 112%.
- Antimony Concentrate,
- arsenic,
- mercury,
- selenium,
- bismuth,
- tin,
- hydride generation atomic fluorescence spectrometry
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