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Citation: Wang Qingmin, Sheng Guihua, Cao Xizhang. THE AXIAL REACTION OF COBALT(Ⅱ) TETRAKIS(4-TRIMETHYL AMINO PHENYL)-PORPHYRIN IODIDE HYDRATE WITH ORGANIC BASES[J]. Chinese Journal of Applied Chemistry, ;1990, 7(6): 58-60. shu

THE AXIAL REACTION OF COBALT(Ⅱ) TETRAKIS(4-TRIMETHYL AMINO PHENYL)-PORPHYRIN IODIDE HYDRATE WITH ORGANIC BASES

1.
Department of Chemistry, Jilin University, Changchun 130023

Received Date: 18 October 1989
Available Online: 1 June 1990

The equilibrium constants and coordination numbers for axial reaction of cobalt(Ⅱ) tetrakis (4-trimethylamino phenyl)-porphyrin iodide hydrate (abb. Co(Ⅱ) TMAPPI) with nitrogen containing organic bases were measured by spectral technique. The results show that Co(Ⅱ)TMAPPI forms 1:2 adducts with imidazoline (Im) and benzimidazoline (PhIm),but 1:1 adducts with pyridine(Py) and n-propylaniline (P₁NH₂). The mechanism of the auxi-liary catalytic effect of nitrogen containing organic bases on the electrocatalytic reduction of CO₂ with Co(Ⅱ)TMAPPI was discussed.
- cobalt tetrakis(trimethylamino phenyl)-porphyriniodide,
- organic base,
- coordination reaction
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