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Citation: Zhang Shuli, Chen Wenqi. CATALYTIC ACTIVITY OF Nd(C₈H₁₁)Cl₂·3THF-R₃Al ON THE POLYMERIZATION OF BUTADIENE[J]. Chinese Journal of Applied Chemistry, ;1990, 7(5): 77-79. shu

CATALYTIC ACTIVITY OF Nd(C₈H₁₁)Cl₂·3THF-R₃Al ON THE POLYMERIZATION OF BUTADIENE

Zhang Shuli ,
Chen Wenqi

1.
Changchun Institute of Applied Chemistry, Academia Sinica, Chongchun 130022

Received Date: 1 August 1989
Available Online: 13 March 1990
Fund Project:

Butadiene was polymerized with the catalyst system composed of Nd(C₈H₁₁)Cl₂·3THF and aluminium alkyls. The experimental results show that the activity of the catalysts de-pends on the aluminium alkyls used,the ratio of Al/Nd and the concentration of the catalysts,but not remarkably affected by solvents. The microstruture of the polymers was independent of the polymerization conditions used.Polybutadicne,with high cis-1,4 content (97-98%) was obtained.
- butadione,
- cyclooctadienyl neodymium dichloride,
- coordination catalytic polymerization
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CATALYTIC ACTIVITY OF Nd(C8H11)Cl2·3THF-R3Al ON THE POLYMERIZATION OF BUTADIENE

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通讯作者: 陈斌, bchen63@163.com

CATALYTIC ACTIVITY OF Nd(C₈H₁₁)Cl₂·3THF-R₃Al ON THE POLYMERIZATION OF BUTADIENE