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Citation: Wan Huijie, Huang Zaifu. SYNTHESIS OF CROWN ETHER COMPOUNDS ⅪⅤ.FERROCENYLPOLYTHIA-CROWN ETHERS AND THEIR SILVER ION-SELECTIVE ELECTRODES[J]. Chinese Journal of Applied Chemistry, ;1990, 7(3): 6-9. shu

SYNTHESIS OF CROWN ETHER COMPOUNDS ⅪⅤ.FERROCENYLPOLYTHIA-CROWN ETHERS AND THEIR SILVER ION-SELECTIVE ELECTRODES

Wan Huijie ,
Huang Zaifu

1.
Department of Environmental Science, Wuhan University, Wuhan 430072

Received Date: 9 June 1989
Available Online: 16 November 1989
Fund Project:

Six of two types ferrocenylpolythia crown ethers(1-6) were prepared by reacting 1,1'-bis(hydroxymethyl) ferrocene or ferrocenccarboxyaldehyde with α,ω-dimercaptan compounds in good yield.A serics of Ag-ion-selective electrodes based on the crown ethers (2-6) as elec-troactive material were prepared. The electrode with 4 was found to have the best properties.It shows linear response of 1×10^-1-3×10^-5mol/L AgNO₃ and potentiometric selectivity co-efficients of 10^-3 and 10^-4-10^-5 for cations of Ⅰ and Ⅱ valency respeetively. The selecti-vities of the electrodes for Na⁺,Hg²⁺, Mg²⁺ were 44-682 times better than other crown ether electrodes reported in literature.
- ferrocenylthia crown ether,
- synthesis,
- ion-selective electrode
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