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Citation: Ma Aizeng, Li Laiming, Lin Yonghua, Zeng Guangfu, Jin Songchun, Li Han. SYNTHESIS AND CRYSTAL STRUCTURE OF LANTHANUM COMPLEX WITH TRIS-(DIMETHYL PHOSPHATE) AND TRIMETHYL PHOSPHATE[J]. Chinese Journal of Applied Chemistry, ;1989, 6(4): 99-103. shu

SYNTHESIS AND CRYSTAL STRUCTURE OF LANTHANUM COMPLEX WITH TRIS-(DIMETHYL PHOSPHATE) AND TRIMETHYL PHOSPHATE

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 8 October 1988
Available Online: 18 January 1989

The title complex was synthesized and characterized by elemental analysis and FT-IR spectrometry. The crystal of the complex, determined by X-ray diffraction method, belongs to monoclinic with space group C2/c and cell parameters a=19.358(8)Å, b=11.841(4)Å,c=21.272(8)Å, β=100.55(3) andZ=4.Dimethyl phosphates coordinate with lanthanums forming a special structure of alternate two-four O-P-O bridges. Trimethyl phosphates are arranged on tho two sides of the eight-membered rings of the double bridges.
- Lanthanum complex,
- Tris-(dimethyl phosphate),
- Trimethyl phosphate,
- Crystal structure
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